理工学部 物質生命理工学科
Profile Information
- Affiliation
- Professor, Faculty of Science and Technology, Department of Materials and Life Sciences, Sophia University(Concurrent)Chairperson of the Department of Materials and Life Sciences
- Degree
- Ph.D.(The University of Tokyo)博士（工学）(東京大学)
- Researcher number
- 90241231
- J-GLOBAL ID
- 200901036804609930
- researchmap Member ID
- 5000003394
- External link
I am engaged in organometallic chemistry, which is the study of organometallic compounds in which carbon atoms and metal atoms are covalently bonded. In particular, I have been studied on early-transition metals such as zirconium compounds. For example, organic synthesis that utilized zirconocene complexes, olefin polymerization catalysts and synthesis of small metalacyclic alkynes and allenes. Recently I have been investigating more environmentally friendly organic reaction processes using water as a reaction medium in the presence of thermo-responsive polymer micelles.
Research Areas
3Research History
7-
Apr, 2010 - Mar, 2021
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Apr, 2007 - Mar, 2009
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Apr, 2007 - Mar, 2009
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Apr, 1999 - Mar, 2007
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May, 1996 - Mar, 1999
Education
3-
Apr, 1991 - Oct, 1991
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Apr, 1986 - Mar, 1988
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Apr, 1982 - Mar, 1986
Awards
3Papers
112-
Organic Chemistry Frontiers, 11(2) 277-283, Jan, 2024 Peer-reviewedInvitedA molecular editing strategy to construct quinoxalinones from chromones and benzimidazolylidene N-heterocyclic carbenes (NHCs) was developed. The C2 atoms of the chromones were incorporated into the quinoxalinones via ring expansion of the NHCs.
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Journal of Organometallic Chemistry, 1001 122883-122883, Nov, 2023 Peer-reviewedLead authorCorresponding author
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Current Organic Chemistry, 27(15) 1347-1356, Aug, 2023 Peer-reviewedLead authorCorresponding authorAbstract: Ruthenium-catalyzed olefin metathesis reactions were conducted in water with thermoresponsiveblock copolymers forming micelles. The block copolymers were prepared by living radicalpolymerization and consisted of a thermo-responsive and hydrophilic segments. The formersegment included poly(N-isopropylacrylamide) or poly(N,N-diethylacrylamide), and the latterpoly(sodium 4-styrene sulfonate), poly(sodium 2-acrylamido-2-methylpropanesulfonate) orpoly(ethylene glycol). Homometathesis, cross-metathesis and ring-closing metathesis reactions proceededto afford the products in moderate to good yields. Extraction efficiency from the reactionmixture was also studied.
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Chemistry – A European Journal, 29(8) e202203396, Feb 7, 2023 Peer-reviewed
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Journal of Organometallic Chemistry, 982 122531-122531, Dec, 2022 Peer-reviewedLead authorCorresponding author
Misc.
3-
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (3) 316-316, Jan, 2013
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触媒, 41(6) 392-394, Sep 10, 1999
Books and Other Publications
7-
CMC publishing Co., Ltd., Mar, 2022 (ISBN: 9784781316635)
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Springer, Mar, 2004 (ISBN: 9783540016069)Stereoselective olefin polymerization using metallocene catalysts
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Maruzen, Mar, 2004 (ISBN: 9784621073209)
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Springer, Jan, 2001 (ISBN: 9783540414025)Olefin Polymerization under High-pressure: Formation of Super-high Molecular Weight Polyolefins
Presentations
105-
The 104th Annual meeting of The Chemical Society of Japan, Mar 18, 2024
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The 104th Annual meeting of The Chemical Society of Japan, Mar 18, 2024
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13th CSJ Chemistry Festa 2023, Oct 19, 2023
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International Congress on Pure & Applied Chemitsry (ICPAC 2023 Bali), Sep 13, 2023 Invited
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ACS Spring 2023, Mar 26, 2023
Research Projects
18-
Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C), Japan Society for the Promotion of Science, Apr, 2021 - Mar, 2024
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Sophia University, Apr, 2019 - Mar, 2022
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Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C), Japan Society for the Promotion of Science, Apr, 2017 - Mar, 2020